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Laser flash photolysis determination of absolute rate constants for reactions of bromine atoms in solution

✍ Scribed by Scaiano, J. C.; Barra, M.; Krzywinski, M.; Sinta, R.; Calabrese, G.

Book ID: 127314643
Publisher: American Chemical Society
Year: 1993
Tongue: English
Weight: 617 KB
Volume: 115
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00071a048

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Laser flash photolysis (at 248 or 308 nm) or aryl iodides in water or water/methanol solutions produces iodine atoms and phenyl radicals. Iodine atoms react rapidly with added I-to form 12-but do not react rapidly with 0 2 ( k I lo7 L mol-l s-l). Iodine atoms oxidize phenols to phenoxyl radicals, wi