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Determination of the Absolute Rate Constants of Reactions between Diphenyl Carbonyl Oxide and Alcohols by Flash Photolysis

✍ Scribed by A. M. Nazarov; S. L. Khursan; I. A. Kalinichenko; S. Kh. Ziganshina; V. D. Komissarov


Book ID
110391230
Publisher
Springer
Year
2002
Tongue
English
Weight
54 KB
Volume
43
Category
Article
ISSN
0023-1584

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Determination of the rate constants for
✍ R. Lesclaux; F. Caralp πŸ“‚ Article πŸ“… 1984 πŸ› John Wiley and Sons 🌐 English βš– 560 KB

The rate constants for reactions (4) and (5) ( 4 ) CFCI,O, 7 NO -+CFCI,O + NO, ( 5 ) CFCI,O, + NO, + M -CFCI,O,NO, -M were determined at room temperature by pulsed laser photolysis and time resolved mass spectrometry. A description of the experimental setup is given. CFCI,O, radicals were generated