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A flash photolysis–resonance fluorescence kinetics study of ground-state sulfur atoms: I. Absolute rate parameters for reaction of S(3P) with O2(3Σ).

✍ Scribed by D. D. Davis; R. B. Klemm; M. Pilling


Book ID
118284901
Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
762 KB
Volume
4
Category
Article
ISSN
0538-8066

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A flash photolysis–resonance fluorescenc
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## Abstract Rate parameters for the reaction of ground‐state atomic sulfur, S(^3^__P__), with the olefins __cis__‐2‐butene and tetramethylethylene have been determined over a temperature range of ∽280°K. A major finding of this study was that the rate constants for both reactions showed negative te