Absolute rate constants for the reaction of S(3P) with ethylene were measured over an ethylene concentration range of 7, a total pressure of 50 to 400 tom, and a flash intensity range of 10. At 298"K, the bimolecular rate constant was found to be invariant over this range of variables a& had a measu
A flash photolysis–resonance fluorescence kinetics study of ground-state sulfur atoms: I. Absolute rate parameters for reaction of S(3P) with O2(3Σ).
✍ Scribed by D. D. Davis; R. B. Klemm; M. Pilling
- Book ID
- 118284901
- Publisher
- John Wiley and Sons
- Year
- 1972
- Tongue
- English
- Weight
- 762 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0538-8066
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## Abstract Absolute rate constants for the reaction of S(^3^__P__) with ethylene episulfide were measured over a C~2~H~4~S concentration range of 5, a total pressure of 20–200 tort, and a flash intensity range of ˜4. Over this range of variables, the bimolecular rate constant was found to be invar
## Abstract Using the technique of flash photolysis‐resonance fluorescence, absolute rate constants have been measured for the reaction of S(^3^__P__) with propene and 1‐butene. Variations in experimental conditions included the following: temperature (215–500°__K__); total pressure a factor of 10;
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