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The reactions of HO with CH2O and of HCO with NO2

โœ Scribed by Boyce M. Morrison Jr.; Julian Heicklen


Publisher
Elsevier Science
Year
1980
Weight
743 KB
Volume
13
Category
Article
ISSN
0047-2670

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๐Ÿ“œ SIMILAR VOLUMES


The reaction of CH3O2 radicals with NO2
โœ Hiroyuki Adachi; Norman Basco ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 881 KB

The rate constant for the reaction CH302 + NO2 -(products) has been measured directly by flash photolysis and kinetic spectroscopy. At room temperature and a t total pressures between 53 and 580 Torr, k:, = (9.2 f 0.4) X lo8 liter/mole sec so that the rate of formation of the probable primary produc

The rate of reaction of HO2 radicals wit
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The rate-coefficients for the reactions HO2 + NO = HO + NO\* (1) and HO\* + HO = Hz0 + 0, (2) have been remeasured by laser magnetic resonance using an improved experimental arrangement. Values of kl = (6-9 f 0.6) X lO-12 cm3 molecule-' s-l and k2 = (5.8 -c 09) X 10-l cm3 molecule-' s-' (one standar

Temperature dependence of the reactions
โœ R. Simonaitis; Julian Heicklen ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 826 KB

Mixtures of N20, Hz, 0 2 , and trace amounts of NO and NO2 were photolyzed at 213.9 nm, at 245'-328'K, and at about 1 atm total pressure (mostly H2). HO2 radicals are produced from the photolysis and they react as follows: (la) Reaction (lb) is unimportant under all of our reaction conditions. Rea

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&te coefficients for the reaction of Cl-I,0 ~th NO 2 were measured over the temperature range 21-O-473 K and over tie pressure range 0 6-4 0 Torr using a flow reactor apparatus uqth laser-Induced fluorescence (LIF) detection of CH,O The results were fitted LO extract recombmatlon and &sproporuonauon

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The hinetics of the reactions of the (CI13)2K rrtduxl wthX0.N02,and O2 rrere studied usins FTIR spectroscopy. The tutwe of the products and the ratio ofr.~tc constants for these reactions acre dctermmed\_ The results were used to evalu.rte the potenti.n for nitros.unine .md nitramine formation in X0