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The reactions of Cl and ClO with the NO3 radical

✍ Scribed by R.A. Cox; R.A. Barton; E. Ljungstrom; D.W. Stocker

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
481 KB
Volume
108
Category
Article
ISSN
0009-2614

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✦ Synopsis

Ik phtrtolysis ol'CI2 in the presence of CIONOa UTIC used as a sxwx of NOJ radicals via the reaction Cl + CIONO, -C1-r + h'O3. Tote kinctirprowh and decay of NO3 uxxc measured using time-rcsoivcd absorption at 661 nm_ The reactions Cl + NOa -Cl0 + iW* (7) snd Cl0 f NO, -X IO-" and /ia = (a.0 r 1.7) x IO-l3 Cl00 + NOI (8) sppuared to be importanr. \vith k7 = (7-6 z 1.11 cm3 moiccuk-5-l at 296 K. A value of I.63 x 1O-'7 cm2 motccuIe-l ~3s determined for the absorption cross section of NO-, at 661 run.

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