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Kinetics of the reaction Cl + O3 → ClO + O2

✍ Scribed by M.S. Zahniser; F. Kaufman; J.G. Anderson

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
536 KB
Volume
37
Category
Article
ISSN
0009-2614

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✦ Synopsis

The bimolecular rate constant for the reaction Cl + 03 -Cl0 + O2 is measured over the temperature range 210 to 360 K in it dischare flow system using Cl nfom rcsonzncc fluorescence at 134-72 nm to monitor the decay of Cl under pseudo fist order conditions. Results, expressed in the form k, = (2.35 i 0.5) X 1O-11 esp[-(171 + 30)/T], arc compared with other recent studies of this reaction. Stratospheric implications are discussed briefly including the possl%ilitY of a concurrent thee-body mechanism with 02 forming ClOs.

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