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Kinetics of the reactions of CH3O with Cl and CIO

✍ Scribed by Véronique Daële; Gérard Laverdet; Gilles Poulet

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
588 KB
Volume
28
Category
Article
ISSN
0538-8066

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✦ Synopsis

The kinetics of the reactions CH,O + CI + H,CO + HCI ( 1 ) and CH,O + ClO -+ H,CO + HOCl ( 2 ) have been studied using the discharge-flow techniques CH,O was monitored by laser-induced fluorescence, whereas mass spectrometry was used for the detection or titration of other species. The rate constants obtained at 298 K are hl = (1.9 5 0.4) X lo-" cm3 molecule-' s-l and h, = ( 2 . 3 2 0 3) X lo-" cm3 molecule-' s-I These data are useful to interpret the results of the studies of the reactions of CH,O, with C1 and CIO which. at least partly. produce CH,O radicals. 0 1996 John Wiley &Sons. Inc

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