✦ LIBER ✦

Kinetics of the reactions of chlorine atoms with CH3ONO and CH3ONO2

✍ Scribed by O. Sokolov; M. D. Hurley; J. C. Ball; T. J. Wallington; W. Nelsen; I. Barnes; K. H. Becker

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 104 KB
Volume: 31
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1999)31:5<357::aid-kin5>3.0.co;2-6

No coin nor oath required. For personal study only.

✦ Synopsis

The kinetics of the reactions of Cl atoms with CH 3 ONO and CH 3 ONO 2 have been studied using relative rate techniques. In 700 Torr of nitrogen diluent at 295

is in good agreement with the literature data. The result for k(Cl ϩ CH 3 ONO) is a factor of 4.5 lower than that reported previously. It seems likely that in the previous study most of the loss of CH 3 ONO which was attributed to reaction with Cl atoms was actually caused by photolysis leading to an overestimate of k(Cl ϩ CH 3 ONO).

📜 SIMILAR VOLUMES

Rate constants for the reactions of OH r

Rate constants for the reactions of OH radicals with CH3OCF2CF3, CH3OCF2CF2CF3, and CH3OCF(CF3)2

✍ K. Tokuhashi; A. Takahashi; M. Kaise; S. Kondo; A. Sekiya; S. Yamashita; H. Ito 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 133 KB 👁 1 views

The rate constants for the reactions of OH radicals with CH 3 OCF 2 CF 3 , CH 3 OCF 2 CF 2 CF 3 , and CH 3 OCF(CF 3 ) 2 have been measured over the temperature range 250-430 K. Kinetic measurements have been carried out using the flash photolysis, laser photolysis, and discharge flow methods combine

Atmospheric chemistry of acetone: Kineti

Atmospheric chemistry of acetone: Kinetic study of the CH3C(O)CH2O2+NO/NO2 reactions and decomposition of CH3C(O)CH2O2NO2

✍ Jens Sehested; Lene K. Christensen; Ole J. Nielsen; Merete Bilde; Timothy J. Wal 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 290 KB 👁 2 views

Pulse radiolysis was used to study the kinetics of the reactions of CH 3 C(O)CH 2 O 2 radicals with NO and NO 2 at By monitoring the rate of formation and decay of NO 2 295 K. using its absorption at the rate constants 400 and 450 nm k(CH C(O)CH O ϩ NO) ϭ (8 Ϯ 3 2 2 and were de-Ϫ12 Ϫ12 3 Ϫ1 Ϫ1 2) ϫ

Gas-phase Reactions of CH3OCH2+ with Alc

Gas-phase Reactions of CH3OCH2+ with Alcohols

✍ Audier, H. E.; McMahon, T. B. 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 277 KB 👁 1 views

As a result of an extensive delocalization of charge and a unique covalent structure, the cation has, in CH 3 OCH 2 ' e †ect, the character of an ambident electrophile. This cation can, on the one hand, be considered to be a classical electrophile. On the other hand, it may be considered to be a fac

Kinetics of the reactions of CH3O with B

Kinetics of the reactions of CH3O with Br and BrO at 298 K

✍ Alfonso Aranda; Véronique Daële; Georges Le Bras; Gilles Poulet 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 142 KB 👁 2 views

A discharge flow reactor coupled to a laser-induced fluorescence (LIF) detector and a mass spectrometer was used to study the kinetics of the reactions CH O ϩ Br : 3 (1) and (2). From the kinetic analysis of CH 3 O by LIF in the products CH O ϩ BrO : products 3 presence of an excess of Br or BrO, th

Tunable diode laser studies of the react

Tunable diode laser studies of the reaction of Cl atoms with CH3CHO

✍ C. S. Kegley-Owen; G. S. Tyndall; J. J. Orlando; A. Fried 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 174 KB 👁 1 views

The reaction Cl ϩ CH 3 CHO : HCl ϩ CH 3 CO (1) was studied using flash photolysis / tunable diode laser absorption spectroscopy to monitor the production of HCl. The rate coefficient, k 1 , was measured to be (7.5 Ϯ 0.8) ϫ 10 Ϫ11 cm 3 molecule Ϫ1 s Ϫ1 at 298 K. HCl (v ϭ 0) and HCl † (v ϭ 1) were mea

Rate constants and Arrhenius parameters

Rate constants and Arrhenius parameters for the reactions of Cl atoms with the halogenated ethers: CF3CH2OCHF2, CF3CHClOCHF2, and CF3CH2OCClF2

✍ Kevin M. Hickson; Ian W. M. Smith 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 179 KB 👁 1 views