## Abstract The rates of several novel elementary reactions involving ClO, BrO and SO free radicals in their ground states were studied in a dischargeโflow system at 295 K, using mass spectrometry. The rate constant __k__~2~ was determined from the decay of SO radicals in the presence of excess ClO
Kinetic studies of free radical reactions by mass spectrometry. I. The reactions SO + NO2 and ClO + NO
โ Scribed by Michael A. A. Clyne; Alexander J. Macrobert
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 897 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0538-8066
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โฆ Synopsis
Abstract
A novel technique is described for forming groundโstate SO X^3^ฮฃ^๏ฃฟ^ radicals free of reactive impurities in a dischargeโflow system. Mass spectrometric detection of SO and ClO free radicals has been used to study the kinetics of the following reactions at 295 K:
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๐ SIMILAR VOLUMES
The reactions Br + NO2 + M -+ BrNOZ + M (1) and I + NOz have been studied at low pressure (0.6-2.2 torr) at room temperature and with helium as the third body by the discharge-flow technique with EPR and mass spectrometric analysis of t h e species. The following third order rate constants were fou
## Abstract The rate constants for the reactions of the DS radical with NO~2~ (reaction 1) and ClNO (reaction 2) have been measured using the dischargeโflow technique at 2 torr total pressure of helium. The DS radical was monitored by laserโinduced fluorescence. The reactions were found to have the
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