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Kinetics of the DS-radical reactions with CINO and NO2

✍ Scribed by Frederick F. Fenter; James G. Anderson

Publisher: John Wiley and Sons
Year: 1994
Tongue: English
Weight: 702 KB
Volume: 26
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550260803

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✦ Synopsis

Abstract

The rate constants for the reactions of the DS radical with NO~2~ (reaction 1) and ClNO (reaction 2) have been measured using the discharge‐flow technique at 2 torr total pressure of helium. The DS radical was monitored by laser‐induced fluorescence. The reactions were found to have the following bimolecular rate constants (95% confidence level, in units of cm^3^ molecule^−1^ s^−1^):
This expression for k~1~ is found to be in excellent agreement with one of several previous studies. The magnitude of k~2~ is examined within the framework of a well‐established reactivity trend. © 1994 John Wiley & Sons, Inc.

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