✦ LIBER ✦

The reaction of ethylperoxy radicals with NO2

✍ Scribed by Hiroyuki Adachi; Norman Basco

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 337 KB
Volume: 67
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)85171-4

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✦ Synopsis

Tile rate constant for the reaction C2H502 + NO 2 ~ products (10) has been measured directly by flash photolysis and kinetic spectroscopy in the pressure range 44-676 Torr. At room temperature klo = (7.5 ± 0.4) × 108 ~ mole -1 s -1 so that the rate of formation of the probable primary product, peroxyethyl nitrate (C2HsO2NO2) may be significant in urban atmospheres.

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