## Abstract The radicalβmolecule reaction mechanism of CHCl~2~ and CCl~3~ with NO~2~ have been explored theoretically at the B3LYP/6β311G(d,p) and MCβQCISD (singleβpoint) levels. For the singlet potential energy surface (PES) of CHCl~2~ + NO~2~ reaction, the association of CHCl~2~ with NO~2~ was fo
The reaction of CCl3 radicals with NO2
β Scribed by J.B. Cumming; R. Cooper; W.A. Mulac; S. Gordon
- Publisher
- Elsevier Science
- Year
- 1980
- Weight
- 279 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0146-5724
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Ihe reactions of CC1302 with NO and NO2 have been studied by steady-state photolqsis of Clz-HCCl,-Oz-&-NO --NOz mixtures at =I atm: CCl30, + NO -Ccl,0 + NO, (3), CCt,O, + NO2 (t hl) \* CCl,02NOt (+ hi) (4. A); k&k3 = 0.68, independent of temperature-The thermal decomposition of CC1302N02 via the bac
The rate constant for the reaction CH302 + NO2 -(products) has been measured directly by flash photolysis and kinetic spectroscopy. At room temperature and a t total pressures between 53 and 580 Torr, k:, = (9.2 f 0.4) X lo8 liter/mole sec so that the rate of formation of the probable primary produc
Acetylperoxy radicals were produced by the flash photolysis of chlorine in the presence of acetaldehyde and oxygen. By adding various concentrations of nitrogen dioxide, the rate constant for the reaction producing PAN was measured to be k, (153 Torr) = (2.29 ? 0.051 X The effect of pressure has be
Tile rate constant for the reaction C2H502 + NO 2 ~ products (10) has been measured directly by flash photolysis and kinetic spectroscopy in the pressure range 44-676 Torr. At room temperature klo = (7.5 Β± 0.4) Γ 108 ~ mole -1 s -1 so that the rate of formation of the probable primary product, perox
## Abstract The rate coefficient for the reaction of CCl~3~ radicals with ozone has been measured at 303 Β± 2 K. The CCl~3~ radicals were generated by the pulsed laser photolysis of carbon tetrachloride at 193 nm. The time profile of CCl~3~ concentration was monitored with a photoionization mass spe