Several organo-transition metal complexes were previously prepared in aqueous solution ; Q., CR-Cr(H20)512+ (1) , CR-COALS-(R = alkyl, aryl) (2) and a series of Vitamin B12 (alkyl cobalamine) model compounds with tetradentate ligand systems (2). Carbon monoxide (CO) insertion reactions into the carb
The reaction of trans-β-bromostyrene with potassium hexacyanodinickelate(I) in the presence of olefins
✍ Scribed by Isao Hashimoto; Membo Ryang; Shigeru Tsutsumi
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 234 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
It is well known that a variety of organic halides react with low-vale& transition metal complexes with concomitant metal-carbon bond formation 1) .
Previously we have reported the reaction of potassium hexacyanodinickelate(1) (A)
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During the course of our studies (1) with d7 transition metal complexes and acetylenic compounds, the reactions of potassium hexacyanodinickelate(I), &Niz(CN)e, (2) were investigated. We now wish to report that aqueous solutions of &Ni2(CN)e will oligomerize disubstituted acetylenic compounds at atm
Fluoro chlorides are maJor products in the reactlon of methyl hypochlonte with certain oleflns 1t-1 the presence of boron trifluoride We would like to report an unexpected reactlon of methyl hypochlorite (CH30C1,L) with certain oleflns in methylene chloride contalnlng a small amount of boron tnfluor
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