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The Reaction of Acetylenic Compounds with Hexacyanodinickelate(I) Ion in Aqueous Solution

✍ Scribed by John P. Martella; William C. Kaska

Publisher: Elsevier Science
Year: 1968
Tongue: French
Weight: 187 KB
Volume: 9
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)72785-7

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✦ Synopsis

During the course of our studies (1) with d7 transition metal complexes and acetylenic compounds, the reactions of potassium hexacyanodinickelate(I), &Niz(CN)e, (2) were investigated. We now wish to report that aqueous solutions of &Ni2(CN)e will oligomerize disubstituted acetylenic compounds at atmospheric pressure with ease. This novel result actually

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