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The reaction of potassium hexacyanodinickelate(I) with organic halides in the presence of carbon monoxide

✍ Scribed by Isao Hashimoto; Membo Ryang; Shigeru Tsutsumi

Publisher: Elsevier Science
Year: 1969
Tongue: French
Weight: 180 KB
Volume: 10
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)88412-4

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✦ Synopsis

Several organo-transition metal complexes were previously prepared in aqueous solution ; Q., CR-Cr(H20)512+ (1) , CR-COALS-(R = alkyl, aryl) (2) and a series of Vitamin B12 (alkyl cobalamine) model compounds with tetradentate ligand systems (2). Carbon monoxide (CO) insertion reactions into the carbon-metal bond of alml (or aryl)-transition metal complexes in aprotic solvents are well known (4). It has, however, been reported that pentacyanobenzylcobaltate [C6H5CH2-Co(CN)513shows no immediate reaction with CO (&) and no reports have yet

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