As a part of our continuing studies on the organic selenium chemistry, we reported that ureas can be synthesized by the reaction of carbon monoxide with ammonia or amines in the presence of selenium catalyst and oxygen. 1,2) The formation of ureas in such cases was interpreted as involving the react
A new synthesis of carbonates. The reaction of carbon monoxide with alkolates in the presence of selenium.
โ Scribed by Kiyoshi Kondo; Noboru Sonoda; Shigeru Tsutsumi
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 102 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
In the previous communication we reported the synthesis of ureas from aliphatic amines and carbon monoxide using selenium as a catalyst!.
๐ SIMILAR VOLUMES
The use of alkylcopper(I) "ate" complexes for alkylation of a wide variety of organic substrates continues to be a subject of active interest. 192 In this context, we wish to report our observations concerning the reaction of several of such complexes with carbon monoxide, a reaction which, under ap
Several organo-transition metal complexes were previously prepared in aqueous solution ; Q., CR-Cr(H20)512+ (1) , CR-COALS-(R = alkyl, aryl) (2) and a series of Vitamin B12 (alkyl cobalamine) model compounds with tetradentate ligand systems (2). Carbon monoxide (CO) insertion reactions into the carb