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Reaction of methyl hypochlorite with certain olefins in the presence of boron trifluoride

✍ Scribed by Victor L. Heasley; Dale F. Shellhamer; Robert K. Gipe; Harry C. Wiese; Melanie L. Oakes; Gene E. Heasley

Publisher: Elsevier Science
Year: 1980
Tongue: French
Weight: 213 KB
Volume: 21
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)93670-0

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✦ Synopsis

Fluoro chlorides are maJor products in the reactlon of methyl hypochlonte with certain oleflns 1t-1 the presence of boron trifluoride We would like to report an unexpected reactlon of methyl hypochlorite (CH30C1,L) with certain oleflns in methylene chloride contalnlng a small amount of boron tnfluorlde, BF3 132 We observed that 1. reacted with methyl acrylate (z), methyl crotonate (L), and methyl isocrotonate (2) to produce fluoro chlorides by the addition of the elements of Cl, F

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