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Novel fluoride transfer in the reaction of tricyclic epoxides with boron trifluoride

✍ Scribed by Naotake Takaishi; Hitoshi Takahashi; Yoshiaki Inamoto

Publisher: Elsevier Science
Year: 1985
Tongue: French
Weight: 237 KB
Volume: 26
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)95099-8

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✦ Synopsis

Reaction of the tricyclic epoxides (la) and (lb) with boron trifluoride etherate leads to fluorohydrins (2a) and (2v derived in the novel fluoride transfer, whereas (lc) undergoes isomerizationto Spiro ketone (3).

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