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Boron trifluoride as a promoter and fluoride donor in the aldol reaction of trans α,β-epoxyaldehydes. Access to 5- and 6-fluoro heptulosonic ester analogues

✍ Scribed by Yvan Ruland; Chantal Zedde; Michel Baltas; Liliane Gorrichon

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 298 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)01442-2

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✦ Synopsis

A direct synthesis of 5-and 6-fluoro heptulosonic esters is achieved by reaction of trans tx,l~-epoxyaldehydes with 2-(trimethylsilyioxy)acrylate in presence of BF3.Et20.

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ChemInform Abstract: Boron Trifluoride a

ChemInform Abstract: Boron Trifluoride as a Promoter and Fluoride Donor in the Aldol Reaction of trans α,β-Epoxyaldehydes. Access to 5- and 6-Fluoro Heptulosonic Ester Analogues.

✍ Yvan Ruland; Chantal Zedde; Michel Baltas; Liliane Gorrichon 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

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