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The reaction of symmetric disulphides with sodium 2-nitropropan-2-ide

โœ Scribed by W.Russell Bowman; Geoffrey D. Richardson

Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
119 KB
Volume
18
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

Reactions of thiolate anions with 2-subs
Reactions of thiolate anions with 2-substituted-2-nitropropanes
โœ W.Russell Bowman; Geoffrey D. Richardson ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 284 KB

Thiolates undergo substitution reactions with 2-substituted-2-nitropropanes by an SRNl mechanism or are oxidised to disulphides by an ionic mechanism.

Effects of methanol solvation on the nuc
Effects of methanol solvation on the nucleophilic reactions of thiolates with 2-substituted-2-nitropropanes
โœ Suleiman I. Al-Khalil; W.Russell Bowman ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 308 KB

Slumnary : MethanoI soZvation prevents S& substitution in the reaction of Me2C(X)NO2 with thioZates and favours an aZternative redox reaction to yieZd disuZphide and nitronate. Thiolates have been shown1p2 to react with 2-substituted-2-nitropropanes in dipolar aprotic