๐”– Bobbio Scriptorium
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Reactions of thiolate anions with 2-substituted-2-nitropropanes

โœ Scribed by W.Russell Bowman; Geoffrey D. Richardson

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
284 KB
Volume
22
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Thiolates undergo substitution reactions with 2-substituted-2-nitropropanes by an SRNl mechanism or are oxidised to disulphides by an ionic mechanism.

๐Ÿ“œ SIMILAR VOLUMES

Effects of methanol solvation on the nuc
Effects of methanol solvation on the nucleophilic reactions of thiolates with 2-substituted-2-nitropropanes
โœ Suleiman I. Al-Khalil; W.Russell Bowman ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 308 KB

Slumnary : MethanoI soZvation prevents S& substitution in the reaction of Me2C(X)NO2 with thioZates and favours an aZternative redox reaction to yieZd disuZphide and nitronate. Thiolates have been shown1p2 to react with 2-substituted-2-nitropropanes in dipolar aprotic