✦ LIBER ✦

Effects of methanol solvation on the nucleophilic reactions of thiolates with 2-substituted-2-nitropropanes

✍ Scribed by Suleiman I. Al-Khalil; W.Russell Bowman

Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 308 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)99911-8

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✦ Synopsis

Slumnary : MethanoI soZvation prevents S& substitution in the reaction of Me2C(X)NO2 with thioZates and favours an aZternative redox reaction to yieZd disuZphide and nitronate.

Thiolates have been shown1p2 to react with 2-substituted-2-nitropropanes in dipolar aprotic

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