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The reaction of sodium phenoxide with 2-chlorocyclohexanone-1,2-C14

โœ Scribed by William B. Smith; Carlos Gonzalez

Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
166 KB
Volume
7
Category
Article
ISSN
0040-4039

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Oxiranylidene intermediate in the reacti
Oxiranylidene intermediate in the reaction of trans-2-chloro-3- tert-butyloxirane with sodium phenoxide.
โœ Harlan L. Goering; Steven D. Paisley ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 226 KB

The reaction of trans-2-chloro-3-(t-butyl)oxirane with sodium phenoxide in acetonitrile to give trans-2-phenoxy-3-(t-butyl)oxirane involves a-elimination to give an oxiranylidene which undergoes a stereoselective stepwise addition of phenol to give product. ## Recently it was shown that reaction of