The reaction of copper-2,9-dimethyl-1,10-phenanthroline with hydrogen peroxide
✍ Scribed by T.M. Florence; J.L. Stauber; K.J. Mann
- Book ID
- 103567382
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 712 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0162-0134
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📜 SIMILAR VOLUMES
The crystal structure of the title compound, [CuCl 2 -(C 14 H 12 N 2 )(H 2 O)], previously reported by Preston & Kennard [J. Chem. Soc. A (1969). pp. 2955±2958], has been redetermined. The recognition of an inversion twin allowed a much better re®nement.
In the title compound, [Cu(C~14~H~12~N~2~)~2~]C~24~H~20~B·CH~2~Cl~2~, Cu^I^ is chelated by two 2,9-dimethyl-1,10-phenanthroline (2,9-Me~2~phen) ligands, in a distorted tetrahedral coordination geometry. The average Cu—N bond length is 2.032 Å, and the interligand dihedral angle is 77.60 (6)°. The co
In the title compound, [CuCl 2 (C 14 H 12 N 2 )(H 2 O)], there are two molecules in the asymmetric unit; both Cu atoms are fivecoordinate with a distorted trigonal-bipyramidal geometry. Molecules are linked into a three-dimensional network by O-HÁ Á ÁCl and C-HÁ Á ÁCl hydrogen bonds. The packing is