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A light-induced redox reaction of bis(2,9-dimethyl-1,10-phenanthroline)copper(I)

✍ Scribed by McMillin, David R.; Buckner, Michael T.; Ahn, Byung Tae.


Book ID
121263733
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
423 KB
Volume
16
Category
Article
ISSN
0020-1669

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Bis(2,9-dimethyl-1,10-phenanthroline)cop
✍ Eckenhoff, William T. ;Pintauer, Tomislav πŸ“‚ Article πŸ“… 2007 πŸ› International Union of Crystallography 🌐 English βš– 195 KB

In the title compound, [Cu(C~14~H~12~N~2~)~2~]C~24~H~20~BΒ·CH~2~Cl~2~, Cu^I^ is chelated by two 2,9-dimethyl-1,10-phenanthroline (2,9-Me~2~phen) ligands, in a distorted tetrahedral coordination geometry. The average Cuβ€”N bond length is 2.032β€…Γ…, and the interligand dihedral angle is 77.60β€…(6)Β°. The co