The reaction of CF3OOCF2OF with fluoroolefins
β Scribed by A. Russo; V. Montanari; W. Navarrini; Darryl D. DesMarteau
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 422 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0022-1139
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π SIMILAR VOLUMES
Rate constants have been measured over the temperature range 245-419 K for the gas-phase reactions of the hydmxyl radical with the hydrofluorocarbons CHF,CF,CF,CHF, and CF&HFCHFCF2CF,. The Arrhenius expressions k (CHF,CF,CFzCHF,) =(7.80i3.40)X10-'3exp[-(1.51~0.26)~103/T] and k(CF,CHFCHFCF~CF,)=(4.21
Reactions of CF3N0 and (CF3)2N0 with hydrides of phosphorus, arsenic and germanium have in some cases led to interesting and novel unsaturated compounds containing P=N, As=N and Ge=N double
The ultraviolet absorption spectrum of CF3CFC102 and the kinetics of the self reactions of CF3CFC1 and CF3CFC102 radicals and the reactions of CFzCFC102 with NO and NO2 have been studied in the gas phase at 295 K by pulse radiolysis/transient UV absorption spectroscopy. The UV absorption cross secti
The rare cocificwn ior the rcact~on oiCF,02 with NO has been mcasurcd at 295 R m hcbum usins 3 ilow tube nmplcd by 2 rnxs spcctromurcr The KIIUC obrlmed ior this raw coeiircicnt was (17 8 f 3 6) x IO-'\* crK3 s-t and iound to bc indcpcndcnr of [Hc] over the range (6 3-16 8) x lOI cmm3. Tbls value is
## Abstract The relative rate technique has been used to determine the rate constants of the reactions of OH radicals with CF~3~CClο£ΎCCl~2~ (__k__~1~), CF~3~CClο£ΎCClCF~3~ (__k__~2~) and CF~3~CFο£ΎCFCF~3~ (__k__~3~). Experiments were carried out at (298Β±2) K and atmospheric pressure using ultrapure nitr