𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The reaction of 2,5-dimethylpyrrole with O2(a1Δg) in the gas phase

✍ Scribed by E. Fiedler; W. Hack

Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
658 KB
Volume
23
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

The chemical reaction of 2,5-dimethylpyrrole (CsHgN) with Oz('A,)

(W)

CsHgN + oz('Ag) -CsHgNOz was studied in the gas phase in an isothermal flow reactor at room temperature and low pressures. The CsHgN concentration profiles were studied under pseudo-first order conditions ([CeHgN], < [Oz('A,)] with mass-spectrometric detection of CsHgN. Oz('As) was produced either in a microwave discharge or in a chemical reaction. The value for the rate constant:

was measured.

The rate constant is compared to the value obtained for the quenching process. The primary product CsHgNO2 was detected by mass spectrometry and the reaction mechanism is proposed. The possibility of using this reaction as a gas phase titration reaction for Oz('AS) is discussed.

📜 SIMILAR VOLUMES

Chemiluminescence of HNO sensitized by O
Chemiluminescence of HNO sensitized by O2(1Δg) in the reaction systems of O(3P) + C3H6 + NO + O2(Δg)/O2 and H + NO + O2(1Δg)/O2
✍ T. Ishiwata; H. Akimoto; I. Tanaka 📂 Article 📅 1974 🏛 Elsevier Science 🌐 English ⚖ 328 KB

The same chemiluminescent spectrum of HNO was obtained in both the reaction systems of 0(3P) + CaHe + NO + 02 (\* A,)/02 and H + NO + 02( 'Ag)/Oa. The reaction mechanism for producing the excited HNO is proposed to be -HNO('A') + 02 ( 'Ag) + HNO(3A", + 0s (3X,) , HNOc3A") + 02 ('A,) --t HNO('A") +

Yields of O2(1Σg+) and O2(1Δg) in the H
Yields of O2(1Σg+) and O2(1Δg) in the H + O2 reaction system, and the quenching of O2(1Σg+) by atomic hydrogen
✍ Diane V. Michelangeli; Kuang-Yul Choo; Ming-Taun Leu 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 998 KB

The generation of metastable O, ('Xg+) and Oz('Ag) in the H + 0, system of reactions was studied by the flow discharge chemiluminescence detection method. In addition to the Oz('Pg') and Oz(' , H0,(2A~oo) + H02(2AlohO), H02(zA~o,) + HO,(zA~oo), and H Oz(2A~oo) --+ H0,(2A&,o) emissions were detected

Kinetics of the reactions of singlet mol
Kinetics of the reactions of singlet molecular oxygen (O21Δg) with organic compounds in the gas phase
✍ Robert E. Huie; John T. Herron 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 662 KB

## Abstract The reactions of singlet molecular oxygen (O~2~^1^Δ~g~) with a series of organic compounds have been studied in the gas phase at 298°K. The concentration of singlet molecular oxygen was determined by titration with 2,5‐dimethylfuran. The titration technique was checked using a photoioni