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Chemiluminescence of HNO sensitized by O2(1Δg) in the reaction systems of O(3P) + C3H6 + NO + O2(Δg)/O2 and H + NO + O2(1Δg)/O2

✍ Scribed by T. Ishiwata; H. Akimoto; I. Tanaka

Publisher: Elsevier Science
Year: 1974
Tongue: English
Weight: 328 KB
Volume: 27
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(74)90219-x

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✦ Synopsis

The same chemiluminescent spectrum of HNO was obtained in both the reaction systems of 0(3P) + CaHe + NO + 02 (* A,)/02 and H + NO + 02( 'Ag)/Oa. The reaction mechanism for producing the excited HNO is proposed to be -HNO('A') + 02 ( 'Ag) + HNO(3A", + 0s (3X,) ,

HNOc3A") + 02 ('A,) --t HNO('A") + O2 c3cg) .

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