The reactions of electrically discharged nitrogen and hydrogen with Oz('a ) were studied in a t7ow syslem using mass spectrometric detection, Tne reaction of N-atoys with Oz('A ) is proba %I y slower than with ground state 02. y;\_$e otQer hand, thy reaciion of H-atoms with 02( A cm molecule set , a
The reaction of O2(1Δg) with atomic nitrogen and with atomic oxygen
✍ Scribed by I.D. Clark; R.P. Wayne
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- English
- Weight
- 247 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The reaction of atomic hydrogen with 02('Ag) has been investigated as a function of temperature, using a fast discharge-flow apparatus equipped for EPR detection of free radical species. The rate constant for the overall reaction was measured as (1.46 f 0.49) X 10-I' exp(-4000 f 200 cal/mol/RT) cm3/
The potcnri.d of the chemical Ol('a) generator as a means of electronic excitation of metal atoms and oxides is demon-3trJtcd m J %tud\ of the reactions of 02(' A) with Pb. The resonant energy trnnsfer process, Pb(3Pc,) + O,('A) 4 Pb(3Pr) + O2 (" x). ir found tu be the lie> for producinp excited Pb
The reaction of 1,3-cyclopentadiene (CPD) with ground-state atomic oxygen O ( 3 P ) , produced by mercury photosensitized decomposition of nitrous oxide, was studied. The identified products were carbon monoxide and the following C4H6 isomers: 3-methylcyclopropene, 1,3-butadiene, 1,2-butadiene, and
## Abstract The reaction of O(^3^__P__) atoms with isobutane has been studied by using the discharge‐flow system described previously [1]. The rate constant was measured from determinations of the isobutane concentration in the presence of an excess of O atoms and is given by __k__~1~ = (7.9 ± 1.4)
## Abstract The reaction of O(^3^__P__) atoms with propanehas been studied at temperatures near 300 K by using a discharge flow system. Oxygen atoms were generated in the absence of molecular oxygen by the reaction N + NO → N~2~ + O, nitrogen atoms having been generated in a microwave discharge. Ra