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The Reaction Cl + NO 2 → ClONO and ClNO 2†

✍ Scribed by Golden, David M.

Book ID
126042483
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
211 KB
Volume
111
Category
Article
ISSN
1089-5639

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It is found that charge-transfer of NO, with Cl, is tst at thermal energy. The Cl, ion reacts with NO, to produce Cl-and NOzCI, and SH-charge-transfers rapidly with both Cl, and NOz. From the exothermicitics implied it is deduced that EA (SH)< HA (NOz) < EA (Clz) or EX (Not) = 2.38 + 0.06 eV and EA