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ChemInform Abstract: Heterogeneous Interconversion Reactions of BrNO2, ClNO2, Br2 and Cl2.

✍ Scribed by A. FRENZEL; V. SCHEER; R. SIKORSKI; CH. GEORGE; W. BEHNKE; C. ZETZSCH

Book ID
101865499
Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Heterogeneous Interconversion Reactions of BrNO 2 , ClNO 2 , Br 2 and Cl 2 .

-The activation energy E A = 89 kJ/mol for the unimolecular decay of BrNO 2 at atmospheric pressure is estimated from the measurement of the temperature-dependent lifetime. The reactive uptake of BrNO 2 and ClNO 2 on water and aqueous solutions is determined. The reactions Br 2 + NO -2 ↔ BrNO 2 + Br -, Cl 2 + NO -2 β†’ ClNO 2 + Cl -and ClNO 2 + Br - ↔ BrNO 2 + Cl -are observed. Formation and loss of BrNO 2 on salt solutions can be investigated as a model substrate for atmospheric sea salt aerosols. -

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ChemInform Abstract: Reaction of AgOCN w
ChemInform Abstract: Reaction of AgOCN with NO, NO2, ClNO2, ClNO, and BrNO: Evidence of the Formation of OCN-NO2 and OCN-NO.
✍ T. M. KLAPOETKE; A. SCHULZ πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 26 KB πŸ‘ 3 views

Reaction of AgOCN with NO, NO2, ClNO2, ClNO, and BrNO: Evidence of the Formation of OCN-NO2 and OCN-NO. -The reactions of title are studied by gas phase IR spectroscopy. The decomposition products observed in the reactions of AgOCN with NO2 and with ClNO2 are compatible with the formation of an inte