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Thermal energy rate constants for the reactions NO−2 + Cl2 → Cl−2 + NO2, Cl−2 + NO2 → Cl− + NO2Cl, SH− + NO2 → NO−2 + SH, SH− + Cl2 → Cl−2 + SH, and S− + NO2 → NO−2 + S

✍ Scribed by D.B Dunkin; F.C. Fehsenfeld; E.E. Ferguson

Book ID
103011961
Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
258 KB
Volume
15
Category
Article
ISSN
0009-2614

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✦ Synopsis

It is found that charge-transfer of NO, with Cl, is tst at thermal energy. The Cl, ion reacts with NO, to produce Cl-and NOzCI, and SH-charge-transfers rapidly with both Cl, and NOz. From the exothermicitics implied it is deduced that EA (SH)< HA (NOz) < EA (Clz) or EX (Not) = 2.38 + 0.06 eV and EA (Clz) = 2.46 + 0.14 eV.

📜 SIMILAR VOLUMES

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✍ Ming-Taun Leu 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 356 KB 👁 1 views

The termolecular rate constant for the reaction C1 + NO, + M has been measured over the temperature range 264 to 417 K and at pressure 1 to 7 torr in a discharge flow system using atomic chlorine resonance fluorescence at 140 nm to monitor the decay of C1 in an excess of NO,. The results are ky = 9.