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Dichlorotrinitrosylvanadium [V(NO)3Cl2]n

✍ Scribed by Priv. Doz. Dr. W. Beck; Dr. K. Lottes; cand. chem. K. Schmidtner

Book ID
101546437
Publisher
John Wiley and Sons
Year
1965
Tongue
English
Weight
227 KB
Volume
4
Category
Article
ISSN
0044-8249

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Thermal energy rate constants for the re
Thermal energy rate constants for the reactions NO−2 + Cl2 → Cl−2 + NO2, Cl−2 + NO2 → Cl− + NO2Cl, SH− + NO2 → NO−2 + SH, SH− + Cl2 → Cl−2 + SH, and S− + NO2 → NO−2 + S
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It is found that charge-transfer of NO, with Cl, is tst at thermal energy. The Cl, ion reacts with NO, to produce Cl-and NOzCI, and SH-charge-transfers rapidly with both Cl, and NOz. From the exothermicitics implied it is deduced that EA (SH)< HA (NOz) < EA (Clz) or EX (Not) = 2.38 + 0.06 eV and EA