The flash photolysis resonance fluorescencc technique has been used to measure the rrtte constant for the rcaction of O(3P) atoms with CION at 10 torr total pressure over the temperature range 225-273 K. The values obtained can be fit to the Arrhenius equation kr = (1.87 f 1.29) X 10-12 exp[ -(692 i
The rate constant for the reaction of O(3P) atoms with ClONO2
โ Scribed by Luisa Tan Molina; John E. Spencer; Mario J. Molina
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 497 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
The O(3P) + CION reaction has been studicd in a fast flow system over the temperature range from 213 to 295 K, using the air-aftereIow technique for the detection of oxygen atoms under pseudo first order conditions. A value of (3.4 z 0.6) x 10-" exp[(-840 + 60)/T] cm3 molecule-' s-' has been obtained for the rate constant.
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