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The pyrolyses of tri- and tetramethylethylene in the presence of nitric oxide

โœ Scribed by H.-P. Schuchmann; K. J. Laidler

Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
448 KB
Volume
4
Category
Article
ISSN
0538-8066

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โœฆ Synopsis

The pyrolyses of trimethylethylene and tetramethylethylene have been investigated in It appears that apart from a unimolecular the presence and absence of nitric oxide. split, e.g.,

a disproportionation reaction such as may play an important role in initiation. Nitric oxide had no effect on Hz production, which is probably a molecular process. There was similar behavior of both compounds in the presence of NO, indicating that the olefinic hydrogen atom does not play a decisive role. Other aspects of the mechanisms are discussed.

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