Aqueous absorption of nitric oxide induced by sodium chlorite oxidation in the presence of sulfur dioxide
β Scribed by Yang, Chen-Lu ;Shaw, Henry
- Publisher
- American Institute of Chemical Engineers
- Year
- 1998
- Tongue
- English
- Weight
- 549 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0278-4491
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## Abstract The spectrum of the intermediate product ascribed to nitrosopentane has been detected in the photolysis of the SO~2~βpentane (RH)βNO mixture. This result has been interpreted in terms of the radical mechanism by assuming the Hβatom abstraction from RH by the excited SO~2~ molecules to b
The kinetics and mechanism of the reaction between nitrous acid and bromine are studied in dilute sulfuric acid medium, using both the stopped-flow method and conventional spectrophotometry. The partial reaction order with respect to Br 2 moderately differs from 1, showing a saturation at a higher c