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The recombination of iodine atoms in the presence of nitric oxide

✍ Scribed by N. Basco; J. E. Hunt

Publisher: John Wiley and Sons
Year: 1978
Tongue: English
Weight: 518 KB
Volume: 10
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550100707

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✦ Synopsis

The recombination of iodine atoms following the flash photolysis of iodine in the presence of nitric oxide is interpreted through the mechanism ki k-i

with k~ = 3.5 X lo9 1.2/rno12-sec; kz = 1 X 10" l./rnol.sec; k3 = 2.1 X LO7 l./mol-sec at 298°K; E3 = 11 kJ/ rnol; and AH"] = 76 f 6 kJ/mol. Lower and upper limits for the equilibrium constant are also established. The absorption spectrum of I N 0 has been extended down to 223 nm and extinction coefficients for the region of 223-310 nrn and 360-460 nm have been measured.

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