✦ LIBER ✦

NO-catalyzed recombination of iodine atoms: Elementary steps of the complex mechanism

✍ Scribed by H. Van Den Bergh; J. Troe

Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 411 KB
Volume: 31
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(75)85038-x

No coin nor oath required. For personal study only.

✦ Synopsis

The Iewmbination of iodine atoms in the presence of NO has been studied by laser flash photolysis in the inert gas He, at pressures between 1 and 200 atm and at temperatures from 320-440 K. The elementary steps of the cornpIes mechanism of the recombination were rebolved. The fall-off curve of the reaction I + NO + He + IN0 + He was measured as well as the equilibrium constant for I + NO =+ INO. The bond energy of IN0 is found to be AH: = 23 r 3 kul mol-'.

📜 SIMILAR VOLUMES

Flash photolysis study of the NO-catalyz

Flash photolysis study of the NO-catalyzed recombination of bromine atoms

✍ H. Hippler; S. H. Luu; H. Teitelbaum; J. Troe 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 English ⚖ 707 KB

## Abstract The recombination of bromine atoms at room temperature has been studied by flash photolysis in the range of 1–100 atm of the inert diluent He, leading to a value for the third‐order rate constant of (1.5 ± 0.2) × 10^15^ cm^6^/mol^2^.sec. In the presence of NO the recombination is consid