ChemInform Abstract: Reaction of Secondary and Tertiary Amines with Nitric Oxide in the Presence of Oxygen.
β Scribed by Takashi Itoh; Yuji Matsuya; Hiromi Maeta; Michiko Miyazaki; Kazuhiro Nagata; Akio Ohsawa
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Reaction of Nitric Oxide with Amines. -NO and NO/O2, respectively, are found to be useful reagents for the aromatization of Hantzsch dihydropyridines (β (II)) and deamination of aromatic amines (β (VI)). -
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Selective Reduction of Secondary Amides to Amines in the Presence of Tertiary Amides. -The transformation is achieved by reduction of secondary amide moieties bearing an activating Cbz group with hydrides. Catalytic hydrogenation of the resulting hemiacetals removes the hydroxyl and the Cbz group t