✦ LIBER ✦

The product polarization of chemiluminescent reactions of orbital aligned Ca(1P1) with CH3I and C2H5I

✍ Scribed by Guo-wen Ding; Wen-sheng Yang; Wei-zhong Sun; Da-li Xu; Guo-zhong He; Nan-quan Lou

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 486 KB
Volume: 220
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)00148-0

No coin nor oath required. For personal study only.

✦ Synopsis

The product polarixation in the beam-gas chemiluminescent reactions Ca( 'Pi) + RI-CaI*+R for different initial Ca eleo tronic orbital alignments are both probed experimentally and calculated with the DIP extension of the DIPR model (the direct interaction with product repulsion (DIPR) model, with product repulsion distributed as in photodissociation (DIP) model). The experimental results show that the product rotational aligmnent is independent of the Ca( 'Pi) orbital alignment and that the distribution of the product rotational vector becomes less anisotropic as the number of carbon atoms in R increased. The reagent alignment sensitivity factors of the reaction Ca( 'Pi) +CH31-CaI*+CH3 are ako investigated.

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