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Excess molar heat capacities CEp,m and excess molar volumes VEm of {x1CH3(CH2)5CH3 + x2CH3C(CH3)2CH2CH(CH3)CH3 + x3CH3C(CH3)2OC2H5 + (1 - x1 - x2 - x3)C2H5OH}(l) I. Binary and quaternary mixtures

✍ Scribed by W. Mier; R.N. Lichtenthaler; A.H. Roux; J.-P.E. Grolier

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
299 KB
Volume
26
Category
Article
ISSN
0021-9614

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✦ Synopsis

Excess molar heat capacities and excess molar volumes of (\left{x_{1} \mathrm{CH}{3}\left(\mathrm{CH}{2}\right){3} \mathrm{CH}{3}+\right.) (\left.x_{2} \mathrm{CH}{3} \mathrm{C}\left(\mathrm{CH}{3}\right){2} \mathrm{CH}{2} \mathrm{CH}\left(\mathrm{CH}{3}\right) \mathrm{CH}{3}+x_{3} \mathrm{CH}{3} \mathrm{C}\left(\mathrm{CH}{3}\right){2} \mathrm{OC}{2} \mathrm{H}{5}+\left(1-x{1}-x_{2}-x_{3}\right) \mathrm{C}{2} \mathrm{H}{5} \mathrm{OH}\right}(\mathrm{l})) and of all the corresponding binary mixtures were determined using a Picker flow calorimeter and a vibrating-tube densimeter. The experimental quaternary results are compared with the values calculated from the binary results using Colinet's equation and an extended Kohler's equation.

πŸ“œ SIMILAR VOLUMES

Excess molar heat capacities CEp,m and e
Excess molar heat capacities CEp,m and excess molar volumes VEm of {x1CH3(CH2)5CH3 + x2CH3C(CH3)2CH2CH(CH3)CH3 + x3CH3C(CH3)2OC2H5 + (1 - x1 - x2 - x3)C2H5OH}(l) II. Ternary mixtures and prediction of quaternary values
✍ W. Mier; R.N. Lichtenthaler; A.H. Roux; J.-P.E. Grolier πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 349 KB

Experimental excess molar heat capacities and excess molar volumes of all possibie ternary mixtures from \(\left\{x_{1} \mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{5} \mathrm{CH}_{3}+x_{2} \mathrm{CH}_{3} \mathrm{C}\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH}_{2} \mathrm{CH}\left(\mathrm{CH}_{3}\ri

Excess molar volumes of {x1CH3CH2COOCH2C
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Excess molar volumes at the temperature 298.15 K were measured for , and {xCH3(CH2)4 CH3 +(1x)CH3(CH2)3OH}. Excess molar volumes were determined using an Anton Paar DMA 60/602 densimeter. The experimental values obtained in this work were compared with results obtained using methods which estimate

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Excess molar volumes at the temperature \(298.15 \mathrm{~K}\) of \(\left[x_{1} \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CO}_{2}\left(\mathrm{CH}_{2}\right)_{2} \mathrm{CH}_{3}+\right.\) \(x_{2} \mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{5} \mathrm{OH}+\left(1-x_{1}-x_{2}\right)\left\{\mathrm{CH}_{

Excess molar volumes of {x1CH3CO(CH2)2CH
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## Excess molar volumes at CH2 )n-2CH3}, (n= 10 or n = 12), and {xCH3(CH2)3CH2Cl + (1x)CH3(CH2)n-2CH3}, (n= 10 or n = 12), were determined using a densimeter Anton Paar DMA 60/602. All the experimental values were compared with the results obtained by empirical expressions for estimating ternar

Excess molar volumes of the ternary mixt
Excess molar volumes of the ternary mixture {x1CH3(CH2)3OH+x2CH3(CH2)4CH3(CH2)4CH3+ (1–x1–x2)CH3(CH2)3NH2} at temperatures of 298.15 K and 313.15 K
✍ M. DomΔ±́nguez; P. Cea; C. Lafuente; F.M. Royo; J.S. Urieta πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 360 KB

Excess molar volumes V E m of the ternary mixture {x1CH3(CH2)3OH+x2CH3(CH2)4CH3 + (1-x1-x2)CH3(CH2)3NH2} at the temperatures 298.15 K and 313.15 K, and the binary mixtures {xCH3(CH2)3OH + (1-x)CH3(CH2)3NH2}, {xCH3(CH2)4CH3 + (1-x)CH3(CH2)3NH2} at T=313.15 K have been determined from density measurem