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Deactivation of I(52P1/2) by CF3I, CH3I, C2H5I, and CH4

✍ Scribed by Z-N. Gu; A. T. Young; P. L. Houston

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
394 KB
Volume
16
Category
Article
ISSN
0538-8066

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✦ Synopsis

The technique of laser photolysis of alkyl and perfluoroalkyl iodides at 266 nm followed by time-resolved detection of the 1.3-pm emission from I*('PLI2) has been used to measure the rate constants for deactivation of I* by CH31, C'HJ, CF31, and CH,. The recommended values are (2.76 2 0.22) x

(2.85 2 0.40) x (3.5 2 0.5) x and (7.52 2 0.12) X lo-',, respectively, in units of cm3 molecule-' s -' .

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