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The photoelectron spectrum of thiazyl cyanide, NSCN

✍ Scribed by A.W. Allaf; R.L. Johnston; R.J. Suffolk

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 186 KB
Volume: 233
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)01422-r

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✦ Synopsis

Thiazyl cyanide, NSCN, has been produced in a flow system by passing thiazyl chloride, NSCI, over heated silver cyanide, AgCN. The He I photoelectron spectrum of NSCN shows prominent bands at 11.33, 13.52, 14.02 and 14.97 eV, in good agreement with ab initio SCF molecular orbital calculations. The first ionisation of NSCN is attributed to the removal of an electron from the weakly bonding 8a' HOMO.

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