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The Photoelectron Spectrum of Tetracyanomethane

✍ Scribed by Hans Bock; Herbert Stafast; Edwin Haselbach; Erwin Maier


Publisher
John Wiley and Sons
Year
1976
Tongue
German
Weight
204 KB
Volume
59
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

The helium (I) photoelectron spectrum of C(CN)~4~ curiously displays ionizations only in two small windows from 13.8 eV to 14.5 eV and from 14.8 eV to 15.5 eV, respectively. A tentative assignment of the numerous overlapping bands – based on a spectroscopically parametrized LCBO MO model – correlates satisfactorily with ionization potentials of other cyano compounds as well as of tetrahalomethanes.


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