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The Photoelectron Spectrum of [18]Annulene

✍ Scribed by Harold Baumann; Jean-Claude Bünzli; Jean Françcois Michael Oth

Publisher: John Wiley and Sons
Year: 1982
Tongue: German
Weight: 251 KB
Volume: 65
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19820650217

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✦ Synopsis

Abstract

The PE. spectrum of [18]annulene has been measured and correlated with MO‐calculations. The experimental ionization energies can only be explained by computing the electronic states of the cation, that is by taking into account the electron correlation and reorganization in the ionic states. The results allow a discussion of the structure of the neutral molecule; they are consistent with a D~6h~point group of symmetry.

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