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The Low-Temperature UV./VIS. Absorption Spectrum of [18]Annulene

✍ Scribed by Harold Baumann; Jean F. M. Oth

Publisher
John Wiley and Sons
Year
1982
Tongue
German
Weight
375 KB
Volume
65
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The UV./VIS. absorption spectrum of [18]annulene has been remeasured in 3‐rnethylpentane at room and at liquid nitrogen (glass) temperature and interpreted by the CNDO/S‐CI‐method. The confrontation of the experimental electronic transitions with the CNDO/S‐CI‐calculated ones favors a structure with D~6h~‐symmetry, i.e, a structure with delocalized π‐bonds.

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