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The partial anodic oxidation of propylene in acetonitrile

✍ Scribed by D. Clark; M. Fleischmann; D. Pletcher

Publisher
Elsevier Science
Year
1972
Weight
581 KB
Volume
36
Category
Article
ISSN
0022-0728

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✦ Synopsis

In an earlier short communication 1 it was reported that the partial electrochemical oxidation of a wide range of aliphatic hydrocarbons is possible in acetonitrile. These oxidations require a high positive potential, and hence the use of a tetrafluoroborate or a hexafluorophosphate as the base electrolyte, but otherwise proceed under the mild conditions of room temperature and pressure and at a smooth platinum anode.

In this paper a detailed investigation of the anodic oxidation of propylene in acetonitrile is reported; the kinetics of the electrode reaction and its application to synthesis are discussed. EXPERIMENTAL

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