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The anodic oxidation of allyl alcohol in acetonitrile

✍ Scribed by F. Sundholm; G. Sundholm

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
300 KB
Volume
19
Category
Article
ISSN
0013-4686

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✦ Synopsis

The kinetics of the anodic oxidation of ally! alcohol in acetonitrile has been studied. At a platinum electrode at low potentials, ~26 V, the reaction is charge transfer controlled and at higher potentials the process becomes diffusion controlled. The reaction is not a simple charge-transfer process, but may proceed via an adsorption step. Controlled potential electrolysis yielded acrolein and polymers as products. The oxidation of ailyl alcohol on pfatinum is probably electrocatalysed by "surface oxides".

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