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The electrogenerative partial oxidation of propylene

โœ Scribed by Gery R. Stafford

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
757 KB
Volume
32
Category
Article
ISSN
0013-4686

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โœฆ Synopsis

The elcctrogenerative allylic oxidation of propylene to acrolein and acrylic acid has been demonstrated on a palladium anode in a 25 % phosphoric acid fuel cell. Open circuit c&l potentials of0.6 V and current densities as high as 5 mA cm --2 have been obtained but electrode inhibition results in a iower steady state current density of about 2 mAcm_' .

Selectivity to one particular product was poor and the influence of temperature and anode potential on product distribution remains unclear.

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