The kinetics of the anodic oxidation of ally! alcohol in acetonitrile has been studied. At a platinum electrode at low potentials, ~26 V, the reaction is charge transfer controlled and at higher potentials the process becomes diffusion controlled. The reaction is not a simple charge-transfer process
The anodic oxidation of cyclohexene-chloride ion mixtures in acetonitrile
โ Scribed by G. Faita; M. Fleischmann; D. Pletcher
- Publisher
- Elsevier Science
- Year
- 1970
- Weight
- 257 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0022-0728
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โฆ Synopsis
As early as 1898, Haber 1, showed that the product of an electrode reaction, the reduction of nitrobenzene, was dependent on the potential of the electrode
2Hรท+ 20
-H20 ~ -H20
๐ SIMILAR VOLUMES
In an earlier short communication 1 it was reported that the partial electrochemical oxidation of a wide range of aliphatic hydrocarbons is possible in acetonitrile. These oxidations require a high positive potential, and hence the use of a tetrafluoroborate or a hexafluorophosphate as the base elec
The anodic oxidation of the borohydride ion in alkaline aqueous solution at various metal electrodes has been investigated by the charging-curve-oscillographic technique. Only at platinum is the ionization of hydrogen unequivocally confirmed, although there is evidence that it can occur at palladium